RTUL offers a wide range of
other Ultrasonic equipment for enhancing chemical reactions or crystallization,emulsions,
dispersion, polymerization, etc in the laboratory or at the plant level. The equipment are
available in various capacities and configurations.
1) Laboratory - Sonicators
2) Inplant - Processors
RTUL also offers other specialized equipment which are as follows:
1) Ultrasonic Drilling machines- for drilling in glass and ceramic substances
2) Ultrasonic Rotary Drilling machine- where conventional drilling and Ultrasonic effects
are necessary |
| Reduction of reaction time using
Ultrasonic- |
Application
of Ultrasonic waves in chemical process for enhancing/making a chemical reaction is
possible. Ultrasonic waves influences the chemical effects and in its presence many
chemical reactions takes place. An action of cavitation is accompanied by certain physical
occurrences in the presence of ultrasonic sound. There is fundamental local pressure
increase and local temperature rise of several 100 degrees in the vicinity of the bubble
collapse. It is not very clear what aspect of cavitation is fundamentally important in
producing chemical reactions. However, it is believed that increase in temperature and
pressure in the presence of ultrasonic sound is the main reason. There are other effects
due to stimulation,free hydrogen irons and the characteristic oscillation of the
cavitation bubbles, which results in high stress concentration. Dissolved gas in the
liquid is also influencing cavitation action. The basic parameters which need to be
established for enhancing any chemical reaction includes frequency of vibration,
intensity,treatment time, pressure, temperature, etc. There are many chemical reactions,
among them are liberation of iodine from potassium iodide solution which is well known.
|
| Crystallisation- |
Influence
of Ultrasonic waves on crystal formation and distribution is well known in molten metals
but a similar effect is experienced in saturated solution of salts. The tendency being the
number crystals centres to be increased and the rate of crystallisation to be more rapid
under influence of ultrasonic. It is reported that the production of multiple crystal
centres is the result of cavitation and if a super saturated solution of the salt is
irradiated, it is often on crystallisation of the salt. In certain salts, Ultrasonic
action helps in preventing local super cooling.
|
| Emulsions- |
Normally
mechanical system is using high-speed stirrers for emulsion, which operate at maximum
20,000 RPM. Use of Ultrasonic for stable emulsion is well established, as the micro
vibration produced in the liquid is of very high speed (typically 20KHz). It means that
Ultrasonic vibration is 100 times as effective as a mechanical stirrer operating at 20,000
RPM. The major emulsions possible include, oil in water and water in oil emulsions,
benzene, toluene, zyline, nitro benzene based emulsions. It is very difficult to list all
the possible emulsions, but one combination is of interest as a striking demonstration of
the ease with which they can be formed by ultrasonic irradiation. If candle wax is allowed
to drip into water while being irradiated, white emulsion is immediately formed possessing
a very high stability. Any emulsion formation is done in two steps. Initially, the two
liquids are mixed or stirred by mechanical system and then exposed to ultrasonic
irradiation. This process gives more stable emulsion and requires less Ultrasonic energy.
To perform more stable emulsion process it is necessary to add emulsifiers.
|
| Dispersion- |
Dispersion
of coherent solids requires more Ultrasonic power than needed for liquid system. Colloidal
solutions can be produced using Ultrasonic sound in substances of moderate cohesion such
as crystals of mica, gypsum,statite, hematite, sulpha and graphite. It is also necessary
that the substances to be dispersed be of microscopic size and even the particle is truly
colloidal solution need to be broken down further by Ultrasonic irradiation. There have
been reports of particle size reduction in vanadium pentoxide (from 15 microns to 3
microns), graphite suspensions, etc.It is also possible to produce metallic colloidal
suspensions in electrolysis or chemical reactions. It is reported with fine grain
dispersion, platinum, gold, copper, mercury, lead, bismuth, nickel,iron and aluminium have
been produced in the presence of Ultrasonic. Dispersion has numbered of industrial
applications, in vegetable beater, textile dyes, paint and pigment industry and is being
implemented with success. It is also possible to achieve selective dispersion by the use
controlled Ultrasonic irradiation.
|